Sulfonated polystyrene/montmorillonite nanocomposite as a new and efficient catalyst for the solvent-free Mannich reaction

Authors

  • Ahmad Reza Massah Department of Chemistry, Shahreza Branch, Islamic Azad University, Shahreza, Isfahan, 86145-311, Iran.
  • Mitra Toghyani Department of Chemistry, Shahreza Branch, Islamic Azad University, Shahreza, Isfahan, 86145-311, Iran.
  • Roozbeh Kalbasi Department of Chemistry, Shahreza Branch, Islamic Azad University, Shahreza, Isfahan, 86145-311, Iran. Razi Chemistry Research Center, Shahreza Branch, Islamic Azad University Shahreza, Isfahan, 86145-311, Iran
Abstract:

Sulfonated polystyrene/montmorillonite nanocomposite (OMMT/PS-SO3H) was prepared and used as a novel, efficient and inexpensive heterogeneous acid catalyst in the one-pot reaction three-component Mannich reaction of ketones, aromatic aldehydes and amines under solvent-free conditions. The catalyst was characterized by XRD, SEM, TG, BET and FT-IR techniques. This method has advantages of high yield, moderate to excellent diasteroselectivity, mild condition, catalyst recyclability, and simple work-up procedure.

Upgrade to premium to download articles

Sign up to access the full text

Already have an account?login

similar resources

sulfonated polystyrene/montmorillonite nanocomposite as a new and efficient catalyst for the solvent-free mannich reaction

sulfonated polystyrene/montmorillonite nanocomposite (ommt/ps-so3h) was prepared and used as a novel, efficient and inexpensive heterogeneous acid catalyst in the one-pot reaction three-component mannich reaction of ketones, aromatic aldehydes and amines under solvent-free conditions. the catalyst was characterized by xrd, sem, tg, bet and ft-ir techniques. this method has advantages of high yi...

full text

Nano TiO2@KSF as a high-efficient catalyst for solvent-free synthesis of Biscoumarin derivatives

An efficient, simple and convenient route is described for the synthesis of biscoumarin (3,3'-(arylmethylene) bis (4-hydroxy-2H-chromen-2-one)) by using of recyclable catalyst TiO2@KSF. In this Method, we synthesis biscoumarin derivatives via 3multi-component reactions (3MCRs) of two equivalent 4-hydroxycoumarin with one equivalent of aromatic aldehydes using 20 mg nano TiO2@KSF as homogeneous ...

full text

Nano TiO2@KSF as a high-efficient catalyst for solvent-free synthesis of Biscoumarin derivatives

An efficient, simple and convenient route is described for the synthesis of biscoumarin (3,3'-(arylmethylene) bis (4-hydroxy-2H-chromen-2-one)) by using of recyclable catalyst TiO2@KSF. In this Method, we synthesis biscoumarin derivatives via 3multi-component reactions (3MCRs) of two equivalent 4-hydroxycoumarin with one equivalent of aromatic aldehydes using 20 mg nano TiO2@KSF as homogeneous ...

full text

ZnO nanoparticles as an Efficient and Reusable Catalyst for Synthesis of Quinoxaline under Solvent Free Condition

1,2-Diketones have been reacted in one-pot method with 1,2-diamines at room temperature with ZnO nanoparticles as a catalyst. ZnO nanoparticles as an available and reusable catalyst is used for the synthesis of Quinoxalinein improved yields.

full text

My Resources

Save resource for easier access later

Save to my library Already added to my library

{@ msg_add @}


Journal title

volume 2  issue 1

pages  41- 49

publication date 2012-01-01

By following a journal you will be notified via email when a new issue of this journal is published.

Hosted on Doprax cloud platform doprax.com

copyright © 2015-2023